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16ml of a gaseous compound CnH3nOm was mixed with 60ml O2 and exploded . The gas mixture on cooling occupies 44ml . After treatement with KOH solution,the volume of gas remaining was 12ml .Deduce the formula of compound.

aman jha , 10 Years ago
Grade
anser 1 Answers
Arun

Last Activity: 4 Years ago

n
​ 
 H 
3n
​ 
 O 
m
​ 
 +[n+ 
4
3n
​ 
 − 
2
m
​ 
 ]O 
2
​ 
 →nCO 
2
​ 
 + 
2
3n
​ 
 H 
2
​ 
 O
Volume before reaction 16 60 0 0
Volume after reaction 0 60−16[n+ 
4
3n
​ 
 − 
2
m
​ 
 ] 16n 24n
Volume of gases left = 60−16[ 
4
7n
​ 
 −d 
2
m
​ 
 ]+16n
                                       44=60−12n+8m
                                       12n−8m=16 ...(i)
Volume of O 
2
​ 
  left = 60−16[ 
4
7n
​ 
 − 
2
m
​ 
 ]12=60−28n+8m     
                                     28n−8m=48 ...(ii)
By equations (i) and (ii) , n=2,m=1
Therefore, the gas is C 
2
​ 
 H 
6
​ 
 O            

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