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Stereoselectivity is the preferential formation in a chemical reaction of one stereoisomer
over another. When the product stereoisomers are enantiomers, the phenomenon is
called enantioselectivity and is quantitatively expressed by the enantiomer excess; when
they are diastereoisomers, it is called diastereoselectivity and is quantitatively expressed by
the diastereomer excess
Whereas stereospecific reactions are those in which diff . stereoisomers of reactant leads to diff . stereoisomer s of product .
Whereas stereospecific reactions are those in which diff . stereoisomers of reactant leads
to diff . stereoisomer s of product .
stereospecificity describes a reaction that necessarily yields a given
stereoisomer because of the mechanism of the reaction, while stereoselectivity
describes a reaction where the mechanism allows for the formation of both
products, but the formation of one of the products is favored. Stereospecificity
always yields 100% of a particular stereoisomer, while stereoselectivity does
not necessarily give 100% of the favored isomer
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