Vikas TU
Last Activity: 8 Years ago
U=a+b(PV)
At constant volume,
Cv =(∂ U/∂ T)v
or
dU = Cv dT
dU = bP dV (at constant volume)
Thus, CvdT = bPdP
integrating both sides, we get
Cv * T = bP^2/2
or
Cv = bP^2/2T...............................(1)
At constant Pressure,
dU/dV = Cp = 0 + bP
and from
Cp =(∂ U/∂ T)p
or
dU = Cp dT
dU = 0 + bP
or
bVdv = Cp dT
integerating both sides we get,
b*V^2/2 = Cp*T
or
Cp = bV^2/2T...................(2)
From eqns. (1) and (2)
Y = Cp/Cv = (bV^2/2T)/(bP^2/2T)
= bV^2/bP^2
= (V/P)^2