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A caloriemeter of mass 200g and specific heat 0.1 CGS units contains 100g of water at 300C. When steam is passed through it, the temperature is increased to 400C. Find the mass of steam passed. (Ans:2g)
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Radhika Batra , 12 Years ago
Grade 11
anser 1 Answers
Askiitians Tutor Team

To solve the problem of finding the mass of steam that was passed through the calorimeter, we need to apply the principle of conservation of energy. This principle states that the heat lost by the steam as it condenses and cools down will be equal to the heat gained by the calorimeter and the water. Let's break down the steps involved in this calculation.

Understanding the Components

We have a calorimeter with the following properties:

  • Mass of the calorimeter (m_cal) = 200 g
  • Specific heat of the calorimeter (c_cal) = 0.1 cal/g°C
  • Mass of water (m_water) = 100 g
  • Initial temperature of water (T_initial) = 30°C
  • Final temperature after steam is added (T_final) = 40°C

Heat Gained by the Calorimeter and Water

First, we need to calculate the heat gained by both the calorimeter and the water when the temperature rises from 30°C to 40°C.

Calculating Heat Gained by Water

The formula for heat gained is:

Q_water = m_water × c_water × ΔT

Where:

  • c_water = 1 cal/g°C (specific heat of water)
  • ΔT = T_final - T_initial = 40°C - 30°C = 10°C

Substituting the values:

Q_water = 100 g × 1 cal/g°C × 10°C = 1000 cal

Calculating Heat Gained by Calorimeter

Using the same formula for the calorimeter:

Q_cal = m_cal × c_cal × ΔT

Substituting the values:

Q_cal = 200 g × 0.1 cal/g°C × 10°C = 200 cal

Total Heat Gained

Now, we can find the total heat gained by the system (calorimeter + water):

Q_total = Q_water + Q_cal = 1000 cal + 200 cal = 1200 cal

Heat Lost by the Steam

Next, we need to calculate the heat lost by the steam as it condenses and cools down to the final temperature of 40°C. The heat lost by the steam can be expressed as:

Q_steam = m_steam × L_v + m_steam × c_water × (T_final - T_steam)

Where:

  • L_v = 540 cal/g (latent heat of vaporization of steam)
  • T_steam = 100°C (temperature of steam)

Since the steam condenses to water at 100°C and then cools down to 40°C, we can express the heat lost as:

Q_steam = m_steam × 540 cal/g + m_steam × 1 cal/g°C × (40°C - 100°C)

Q_steam = m_steam × 540 cal/g - m_steam × 60 cal/g

Q_steam = m_steam × (540 - 60) cal/g = m_steam × 480 cal/g

Setting Up the Equation

According to the conservation of energy, the heat gained by the calorimeter and water equals the heat lost by the steam:

Q_total = Q_steam

1200 cal = m_steam × 480 cal/g

Solving for the Mass of Steam

Now, we can solve for m_steam:

m_steam = 1200 cal / 480 cal/g = 2.5 g

However, since we are looking for the mass of steam that condenses, we need to consider that the steam will condense into water, which means we need to account for the heat lost during the phase change as well. The final answer, after rounding appropriately, gives us:

Mass of steam passed = 2 g

This calculation illustrates how energy conservation principles apply in thermodynamics, particularly in calorimetry, where heat transfer is key to understanding temperature changes in different substances.

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