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Schottkey defect is the vacancy found in the crystal lattice of ionic compounds due to size difference in cations.
Here, we know that Ca is a divalent cation and remains as Ca+2 while silver is a univalent cation and remains as Ag+ .
So, when CaCl2 is added to AgCl, then one Ca+2 ion will replace two Ag+ ions which will create a vacancy in place of one Ag+ ion and so there will be the Schottkey defect in the compound.
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