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The graphite rods dipped in pure aluminium and Cu–Al alloy rod at the bottom in the impure aluminium work as conductors. On electrolysis, aluminium is deposited at cathode from the middle layer and equivalent amount of aluminium is taken up by the middle layer from the bottom layer (impure aluminium). Therefore, aluminium is transferred from bottom to the top layer through middle layer while the impurities are left behind. Aluminium thus obtained is 99.98% pure.
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Sumit Kumar
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