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Grade: 11
        
Give the brief mechanism of dehydration of alcohols in organic chemistry
5 months ago

Answers : (1)

Arun
11425 Points
							
Dear student
 

Alcohol upon reaction with protic acids tends to lose a molecule of water to form alkenes. These reactions are known as dehydration of alcohols. Dehydration of alcohols is an example of elimination reaction. It’s rate varies for the primary, secondary and tertiary alcohols. This variation of rate can be attributed to the stability of carbocation generated. Since the carbocation is most stable in case of tertiary alcohols, the rate of dehydration is highest for tertiary alcohols in comparison to secondary and primary alcohols. Dehydration of alchohols follows a three step mechanism:

  1. Formation of protonated alcohol
  2. Formation of carbocation
  3. Formation of alkenes
 

Mechanism of dehydration of alcohols: Dehydration reaction of alcohols can follow E1 or E2 mechanism. For primary alcohols elimination reaction follows E2 mechanism while for secondary and tertiary alcohols elimination reaction follows E1 mechanism. Generally it follows a three step mechanism. The steps involved are explained below:

  1. Formation of protonated alcohol: In this step, the alcohol is acted upon by a protic acid. Due to the lone pairs present on oxygen atom it acts as a Lewis base. Protonation of alcoholic oxygen takes place which makes it a better leaving group. It is a reversible step which takes place very quickly.
  2. Formation of carbocation: In this step, the C-O bond breaks generating a carbocation. This step is the slowest step in the mechanism of dehydration of alcohol. Hence, the formation of carbocation is considered as the rate determining step.

 

  1. Formation of alkenes: This is the last step in dehydration of alcohols. Here the proton generated is eliminated with the help of a base. The carbon atom adjacent to the carbocation breaks the existing C-H bond to form C=C. Thus, an alkene is formed.
5 months ago
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