Anjali Ahuja
Last Activity: 10 Years ago
Hi student
The major cause for lanthanide contraction is due to the inappropriate shielding of the 4f electrons due to the improper shape of the f-orbitals. As the atomic number increases in the lanthanide series, for every proton in the nucleus the extra electron goes to fill the 4f-orbitals.
This results in gradual decrease in the size of lanthanides with increasing atomic number. The decrease in size is not regular throughout the lanthanides. A rapid decrease is seen only in the first six elements compared to the rest of the elements.