Sir,can you please explain how rate constant expression for zero order has been derived and is it true that time taken t1/2is exactly 1/2 times time taken for completion of reaction in case of zero order?How can you prove it?

Dear Sidharth,

Rate constant is dependent onthe factors that canbe determined through experiments only and it may be a coincidene that the rate constant expression powers are equal to the  stitiometric coefficents.

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