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Grade 12Organic Chemistry

Why does the coupling of anilline take place in acidic medium?????

Profile image of sarvesh
10 Years agoGrade 12
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Profile image of Bhavya
10 Years ago
Diazonium coupling is decisively influenced by the pH value of the reaction mixture. Strong basic solutions must be prevented, as diazonium cations are stable only under acidic and moderately basic conditions. Diazonium coupling in connection with amines is carried out in faintly acidic solutions in order to ensure an as high as possible diazonium cation's as well asunprotonatedaromatic amine's concentration. The result of low pH values is a largely protonated and, thus, deactivated aromatic amine, while higher pH values would cause lower diazonium cation concentration.
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