Question icon
Grade 12Organic Chemistry

Why does formic acid give a positive test with tollens reagent?

Profile image of Priyanshi
9 Years agoGrade 12
Answers icon

1 Answer

Profile image of Umakant biswal
9 Years ago
dear priyanshi
formic acid is unique amongst simple carboxylic acids since it contains a hydrogen atom instead of an alkyl group(H-COOH,)all other carboxylic acid contains an alkyl group attached to C instead of hydrogen on left side) ....thus formic acid may be regarded both as an aldehyde as well as a carboxylic acid..like aldehydes it can be easily oxidised to carbonic acid (H2CO3) which decomposes to give CO2 and H2O. 
HCOOH + [O] -----> [H2CO3] ----> CO2 + H2O 

thus like aldehydes it reduces Fehling's solution to red ppt. of Cu2O.Tollen's reagent to silver mirror.
hope it clears now 
regards