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Dipole moments:-
CH3Cl = 1.860 DebyeCH3F = 1.847 Debye
Due to high electron density on flourine its partial charge is less...also C-F bond length is less 139 pm..While C-Cl bond length is 178 pm and also partial charge on Cl is more...
So according to the formula of Dipole moment..
Dipole moment = Partial charge on atom * Bond length..
CH3Cl has more dipole moment than CH3F...
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