Which is a more stable carbocation :triphenyl carbocation or trimethyl carbocation
Jupjyot , 8 Years ago
Grade 12
Organic Chemistry> Which is a more stable carbocation :triph...
2 AnswersSpriha sil
Triphenyl carbocation is a more stable carbocation than trimethyl carbocation.This is due to -I effect in methyl groups which is absent in phenyl.
sreehari
Triphenyl carbocation is stabilized through resonance. The positive charge is delocalized among all three phenyl groups.
The trimethyl cation is stabilized through Hyperconjugation of 9 Hydrogens and +I effect . This gives lower stabilization compared to the delocalization of positive charge in triphenyl carbocation.
Hence triphenyl carbocation is more stabler than trimethyl carbocation.
Approved Last Activity: 8 Years ago
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