which has greater -i power-OR or -OH
which has greater -i power
-OR or -OH
shubham , 10 Years ago
Grade 12th pass
Organic Chemistry> which has greater -i power -OR or -OH...
2 Answers
Sunil Kumar FP
Last Activity: 10 Years ago
OH has greater -i power.Beacuse the R group has the ability to donate electron.It has electron pulling tendendency
Relative inductive effects have been experimentally measured with reference to hydrogen, in decreasing order of -I effect or increasing order of +I effect, as follows:
–NH3+ > –NO2 > –SO2R > –CN > –SO3H > –CHO > CO > –COOH > –COCl> –CONH2 > –F > –Cl > –Br > –I > –OH > –OR > –NH2 > –C6H5 > –CH=CH2 > –H
Relative inductive effects have been experimentally measured with reference to hydrogen, in decreasing order of -I effect or increasing order of +I effect, as follows:
–NH3+ > –NO2 > –SO2R > –CN > –SO3H > –CHO > CO > –COOH > –COCl> –CONH2 > –F > –Cl > –Br > –I > –OH > –OR > –NH2 > –C6H5 > –CH=CH2 > –H
shubham
Last Activity: 10 Years ago
in compounds like ROR and ROH ,we know bond angle of ROR >ROH which implies that % of s character on ROR’s oxygen is more that ROH’s oxygen ,so EN value of oxygen is more in ether than alcohol’s ,so it should have greater tendency to pull electrons so its -i should be greater than that of -OH ….
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