What are exceptions to Ortho effect in determining acidity in substituted benzoic acid?
Shashwat , 9 Years ago
Grade 12
Organic Chemistry> What are exceptions to Ortho effect in de...
2 AnswersVikas TU
At ortho position there is a chance of the formation of the intra-H bonding with the -OH group of the carboxylic acid.
Therefore there would be a fluctuation in determining the acidity.
Therefore there would be a fluctuation in determining the acidity.
TAS
Ortho effect doesn`t operate in case of OH , F and NH2 due to intermolecular h- bonding with H atom of COOH group.
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