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LiAlH4 is a very very powerful reducing agent. It reduces some of the following organic compounds as follows:
However, LiAlH4 cannot reduce non-polar bond like carbon-carbon double bond or triple bonds, that is, it does not reduce alkenes or alkynes to alkanes.
Lithium Aluminium Hydride cannot reduce isolated carbon-carbon double bonds and arenes. LiAlH4 provide hydride ions.
These cannot attack an electron rich carbon-carbon double bond, or be attacked by a pair of negative electrons from a pi orbital.
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