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Grade: 12
        Para nitrophenol is having lower pKa value than phenol becauseA)  phenol is more acidic than p-nitro phenolB)  anion of p-nitrophenol is more stabilised by resonance than that of phenolC)  degree of ionisation of p-nitro phenol is less than that of phenolD)  anion of p-nitrophenol is less stable than that of phenol
2 years ago

Answers : (1)

Vikas TU
9468 Points
							
Because, Anion of p-nitrophenol is more stabilised by resonance than that of phenol.Due to NO2 group attached to the para position it shows -M effect badly which is not in the case for simple Phenol.
2 years ago
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