How basic character and nucleophilic character inversely proportional to one another?
How basic character and nucleophilic character inversely proportional to one another?
Rai , 9 Years ago
Grade 12
Organic Chemistry> How basic character and nucleophilic char...
1 Answers
Beenu Mathew
Last Activity: 9 Years ago
Hi ,
It is not always inversely proportional
- when compounds in the question have the same nucleophilic centre then nucleophilicity parallels basicity. (EX; CH3O-> CH3COO-)
- when compounds in the question have different nucleophilic centre but are present in the same group then what you said is true. (how because in this case we target electronegativity)(I->Br->Cl-..larger atomic mass more nucleophilicity)
- when compounds in the question have different nucleophilic centre and are not in the same group the yet again what you said becomes true. (because of electronegativity)
Thank you,
JEHOYESJIRA
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