Does salicylaldehyde react with NaOH to have a self condensation through a cannizzaro mechanism?!
Does salicylaldehyde react with NaOH to have a self condensation through a cannizzaro mechanism?!
Nahid , 6 Years ago
Grade 12th pass
Organic Chemistry> Does salicylaldehyde react with NaOH to h...
3 Answers
Arun
When you mix the two together, they can react and condense into one molecule. Adding base (such as NaOH) to an aldehyde or ketone will generate a little bit of enolate, which can reaction with another carbonyl molecule. This reaction is called the aldol condensation
Nahid
thanks for your answ
Nahid
Thanks for your answer Arun. But my question is: in salicylaldehyde can’t the phenolic OH in ortho position limit the reaction?! For example the bis(2-hydroxy)methan is produced as the main product
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