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in dark it forms alpha,alpha''-dichloro diethyl ether
in light it forms perchloro diethyl ether
there are two cases-
1) when methyl ketones (R–CO–CH3 ) react with chlorine in present of a base haloform reaction takes place and chloroform ( CHCl3 ) is obtained along with RCOO-
2) Under acidic reaction conditions, selective monohalogenation at the a-postion is observed when the aldehyde or ketone has a hydrogen at α(alpha) position which is more enhanced if hydrogen is more acidic in nature. the reaction is a nucleophillic substituion reaction.
vikash kumar
Btech. IIT Delhi
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