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Grade 12Organic Chemistry

what is the order of reaction in a cannizaro reaction

Profile image of rishabh
12 Years agoGrade 12
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2 Answers

Profile image of rishabh
12 Years ago

since two aldehydes participate along with oh therefore the order of reaction is three 

Profile image of Vikash Kumar
ApprovedApproved Tutor Answer12 Years ago

overall the reaction is a third-order reaction. It is second order wrt aldehyde and first order wrt base:-

rate = k[RCHO]2[OH] 

however at very high base concentration a second path (k'') becomes important and it becomes second order wrt base:-

rate = k[RCHO]2[OH-] + k''[RCHO]2[OH-]

for exams generally consider the first argument i.e. it is a third order reaction

vikash kumar

Btech. IIT-Delhi