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Phenol will be more acidic than thiphenyl as both are in conjucgation but it doesn''t matters.
In Phenol -OH group induces less +M effect than -SH group in phenyl.
And acid character is inversely proportional to +M and +I.
that''s why.
PLZ APPROVE!
Thiophenol has appreciably greater acidity than does phenol. Thiophenol has a pKa of 6 vs 10 for phenol.This is because the lone pair of sulphur is more easily given to ring(than in phenol) and stabilised after losing the H+. Since the conjugate base is more stable the acid is more acidic.
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