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In acqueous solution,the order of basicity is in order.....
(CH3))NH > CH3NH2 > (CH3)3N > NH3
In aq.solution,solvation effect of amines come into playThe solvation of primary and secondary ammonium ion is more than those of tertiary amines.Hence the tertiary amines becomes less acidic.The order becomes
(CH3)2)NH > CH3NH2 > (CH3)3N > NH3
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