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What does the oxidative cleavage of cyclic ketones in presence of acidic KmnO4 yield? Is it a oxo carbooxylic acid or a dibasic carbooxylaic acid???
Dear Swapnil,
Description: Alkenes treated with KMnO4 are cleaved into carbonyl compounds. The type of carbonyl compound depends on the substitution pattern of the alkene.
Notes: The reaction is generally run with aqueous acid and heat.
Examples:
Notes: Note that all C–H bonds attached to alkenes are oxidized to C–OH bonds, but alkene carbons with only carbons attached become ketones. Note that the last example is a cyclic alkene that goes to a linear product.
Mechanism: The detailed mechanism for this reaction is generally not considered important for the purposes of Org 1 / Org 2, although the first step is dihydroxylation of the alkene.
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