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the compound must have either a CH3-C=O group or CH3-CH-OH group
The iodoform test or iodoform reaction is a qualitative chemical test for the detection of ketones and aldehydes carrying an alpha methyl group. The reagents are iodine and sodium hydroxide.Only methyl ketones, or alcohols with the feature:CH3CH(OH)-R may undergo this reaction.There are three steps to the iodoform reaction when starting from an alcohol. If the reaction starts from a methyl ketone, the first step is not needed.Addition of I2(aq) (usually I2 dissolved in KI, shown here reacting with 2-propanol) 2 NaOH + I2 + CH3CH(OH)CH3 → 2 NaI + CH3COCH3 + 2 H2O oxidizes the hydroxyl group to a ketone,The ketone formed reacts with the I2(aq) in a substitution reaction to produce a triiodoketone, for example triiodoacetone. CH3COCH3 + 3I2 → CH3COCI3 + 3HI (Thus, ketone and aldehyde with structure -COCH3 also show positive results). Ethanal is the only aldehyde to give the iodoform reaction.Finally, OH- (aqueous) is added, which reacts with, for example, the triiodoacetone. CH3COCI3 + OH- → CHI3 + CH3COO- Iodoform, or triiodomethane (I3CH) is a pale yellow substance. It is therefore a solid at room temperature. It is insoluble in water and has an antiseptic smell.
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Dear SOHAN SARANGI,
The compounds that will undergo Iodoform test will be having a
CH3CH(OH)- group (or) CH3C=O group .
All the Very Best & Good Luck !!
Hope this helped you immensely...
Regards,
AskIITians Expert,
Godfrey Classic Prince
IIT-Madras
Please approve my answer if you liked it by clicking on "Yes" given below...!!
aldehydes containing hydrogen attached to carbonyl group can easily be hydrated ,hence can easily give tollen's test.just see the mechanism and find the r.d.s and u know wht will effect reactivity!!!!!!!!
if u need further help contact me!!!!
-annesha debroy(iit karagpur)
see..iodoform test is given by (normally) compounds with a keto methyl group but, if there is a secondary or primary alcohol with an adjacent methyl group then also it will be oxidised to give keto methyl gr and thus will give iodofrm tst
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