Flag Organic Chemistry> Electronegativity of Hydrogen isotopes...
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hydrogen has three isotopes: Protium ( 1 proton) , Deuterium ( 1 proton and 1 neutron), and tritium (1 proton and 2 neutrons).

which of these isotopes is most electronegative and why?

Janani Ramesh , 14 Years ago
Grade 11
anser 3 Answers
Godfrey Classic Prince

Dear Janani,

Protium would have the highest electronegativity value followed by Deutrium & then finally tritium ..

The electronegativity decreases in the order..

       Protium(1H1)>Deutrium(1H2)>Tritium(1H3)

 

This is because electronegativity is the tendency to attract the shared pair of electrons towards a particular atom..Now for Protium(1H1) it has one proton(+ve charged) & so it could attract the electrons effectively towards itself but in deutrium there is an added neutral charge in the form of a neutron which increases the size thus reduces the electronegativity tendency of the deutrium atom & similarly for tritium..!!

 

If you still have any doubts then please ask them all so as to clarify them..!!

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Last Activity: 14 Years ago
Nimon B

as we increase the no. of electrons in s orbital, we have a strong shielding from s orbital..... so net effective charge on the adjacent atom's electrons decreses....hence its electronegativity decreses.....

Thus, Protium has largest electro-vetivity...... Smile

Last Activity: 14 Years ago
Emin
Why does  increasing the nucleus size cause reduces elecrtonegativity ? We didnt charge charge , and  there is nothing about size of particles  in electric field  formula.
(q1 . q2 .k /d²)
Last Activity: 4 Years ago
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