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what is hyperconjugation effect? how it explain the stability of alkenes

kiran josan , 14 Years ago
Grade 11
anser 7 Answers
Durgesh Prasher

1242_25758_double bond.jpeg

Last Activity: 14 Years ago
vikas askiitian expert

When atoms / groups having lone pair of electrons are bonded by a single bond to the conjugated system, they displace electrons towards multiple bonds.

illustration of hyperconjugation with single bond
  • When electronegative atoms or group of atoms bond themselves to the conjugated systems by multiple bonding they pull electrons from the multiple bond.
  • illustration of hyperconjugation with multiple bond

This conjugation between electrons of single (H-C) bond with multiple bonds is called hyperconjugation. This occurs when the sigma (s) electrons of the H-C bond that is attached to an unsaturated system, such as double bond or a benzene ring, enter into conjugation with the unsaturated system.


Stability order of alkenes


Last Activity: 14 Years ago
Sushmita
If sigma electrons containing acidic H are present at alternate position with πelectron system, then sigma electrons enter into conjugation with π electron system
Last Activity: 8 Years ago
pragati dound
Hyperconjugation means transfer of the sigma electron which are there in between C-H bond to the next carbon which is attached to alfa carbonMore the number of alfa hydrogenAnd then more the number of hyperconjugation structure which leads to stability.
Last Activity: 8 Years ago
Ram kumar
In a system having double, triple, bonds the ¶(sigma bond) is least contributing to the stability of compound since it is not fulfilling the basic cond. of resonance therefore ¶ bond b/w (C-H) is considered as evil and is pressurized by other bonds hence H of -(CH) is sent outside but within the electrostatic range of C ( * bond b/w C-H is not broken since b.e greater than reso_ energy that will lead to instability.) So( -)ve charge comes on C atom which shares it to pure p orbital of other C atom )and makes π bond , now all members of compound are happy & shows max stabily leading to Hyper conjugation . H atom which goes outside is called alpha H more the no of H atoms which goes outside more is hyperconjugation.
Last Activity: 8 Years ago
Shohan Ahmed
In hyperconguhative effect first need a double bond between c atom (c=c). Besides * carbon called alpha carbon who realise a hydrogen ion than the election made a double bond between alpha and * carbon .And than the other double bond election go through the beside the * carbon hade.
Last Activity: 7 Years ago
Anshika
Hyperconjuation is the interaction of the electron in a sigma orbital with an adjacent empty non bonding orbital,antibondingsigma or pie orbital,to give an extended molecular orbital. Increased electron delocalization associated with hyperconjuation increases the stability of the system 
Last Activity: 7 Years ago
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