When atoms / groups having lone pair of electrons are bonded by a single bond to the conjugated system, they displace electrons towards multiple bonds.

- When electronegative atoms or group of atoms bond themselves to the conjugated systems by multiple bonding they pull electrons from the multiple bond.
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This conjugation between electrons of single (H-C) bond with multiple bonds is called hyperconjugation. This occurs when the sigma (s) electrons of the H-C bond that is attached to an unsaturated system, such as double bond or a benzene ring, enter into conjugation with the unsaturated system.
Stability order of alkenes