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what is condition for carboxylic acid to undergo decarboxylation?& if it does not gives decarboxylation then what other products may form after heating? what is condition for carboxylic acid to undergo decarboxylation?& if it does not gives decarboxylation then what other products may form after heating?
Dear student, Decarboxylation is one of the oldest organic reactions, since it often entails simple pyrolysis, and volatile products distill from the reactor. Heating is required because the reaction is endergonic (unfavorable). Yields are highly sensitive to conditions. In retrosynthesis, decarboxylation reactions can be considered the opposite of homologation reactions, in that the chain length becomes one carbon shorter. Metals, especially copper compounds, are usually required. Such reactions proceed via the intermediacy of metal carboxylate complexes. Decarboxylation of aryl carboxylates can generate the equivalent of the corresponding aryl anion, which in turn can undergo cross coupling reactions. Please feel free to ask your queries here. We are all IITians and here to help you in your IIT JEE preparation. All the best. Win exciting gifts by answering the questions on Discussion Forum. So help discuss any query on askiitians forum and become an Elite Expert League askiitian. Now you score 5+15 POINTS by uploading your Pic and Downloading the Askiitians Toolbar respectively : Click here to download the toolbar.. Askiitians Expert Sagar Singh B.Tech, IIT Delhi
Dear student,
Decarboxylation is one of the oldest organic reactions, since it often entails simple pyrolysis, and volatile products distill from the reactor. Heating is required because the reaction is endergonic (unfavorable). Yields are highly sensitive to conditions. In retrosynthesis, decarboxylation reactions can be considered the opposite of homologation reactions, in that the chain length becomes one carbon shorter. Metals, especially copper compounds, are usually required. Such reactions proceed via the intermediacy of metal carboxylate complexes.
Decarboxylation of aryl carboxylates can generate the equivalent of the corresponding aryl anion, which in turn can undergo cross coupling reactions.
Please feel free to ask your queries here. We are all IITians and here to help you in your IIT JEE preparation. All the best. Win exciting gifts by answering the questions on Discussion Forum. So help discuss any query on askiitians forum and become an Elite Expert League askiitian. Now you score 5+15 POINTS by uploading your Pic and Downloading the Askiitians Toolbar respectively : Click here to download the toolbar.. Askiitians Expert Sagar Singh B.Tech, IIT Delhi
Please feel free to ask your queries here. We are all IITians and here to help you in your IIT JEE preparation.
All the best.
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Sagar Singh
B.Tech, IIT Delhi
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