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Grade upto college level Modern Physics

which of the following statements about hydrogen spectrum is/are correct??
(a) all the lines of Lyman series lie in ultraviolet region
(b) all the lines of Balmer series lie in visible region
(c) all the lines of Paschen series lie in infrared region
(d) none of these
the soln given says that only option a and c are correct..
why not option b????
then why do we say that balmer series lies in visible region????

Profile image of Deepak Patra
12 Years agoGrade upto college level
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1 Answer

Profile image of Askiitians Tutor Team
ApprovedApproved Tutor Answer1 Year ago

To address your question about the hydrogen spectrum and the specific series of spectral lines, let's break down each statement regarding the Lyman, Balmer, and Paschen series to clarify why options (a) and (c) are correct, while (b) is not entirely accurate.

Understanding the Hydrogen Spectrum

The hydrogen spectrum consists of several series of spectral lines that correspond to electron transitions between energy levels in a hydrogen atom. Each series is named after the scientist who studied it, and they are categorized based on the region of the electromagnetic spectrum they occupy.

Examining Each Series

  • Lyman Series: This series involves transitions where electrons fall to the first energy level (n=1) from higher levels (n=2, 3, 4, etc.). All lines in the Lyman series are indeed in the ultraviolet region, which is why statement (a) is correct.
  • Balmer Series: The Balmer series includes transitions where electrons fall to the second energy level (n=2) from higher levels (n=3, 4, 5, etc.). While it is true that the first few lines of the Balmer series (like H-alpha) are in the visible region, there are also lines in the Balmer series that extend into the ultraviolet region. This is why statement (b) is not entirely correct; not all lines are in the visible spectrum.
  • Paschen Series: This series involves transitions to the third energy level (n=3) from higher levels (n=4, 5, etc.). All lines in the Paschen series are found in the infrared region, confirming that statement (c) is accurate.

Clarifying the Balmer Series

When we refer to the Balmer series as lying in the visible region, we typically mean that the most prominent lines, such as H-alpha (red), H-beta (blue-green), and H-gamma (blue), are indeed visible to the human eye. However, the series does extend into the ultraviolet range, which is why it cannot be said that all lines are strictly in the visible spectrum.

Conclusion on the Statements

In summary, the correct statements about the hydrogen spectrum are that all lines of the Lyman series are in the ultraviolet region (a), and all lines of the Paschen series are in the infrared region (c). The Balmer series does include visible lines, but it also has ultraviolet lines, making statement (b) incorrect. This nuanced understanding is essential when studying atomic spectra and their implications in fields like astrophysics and quantum mechanics.