Flag Inorganic Chemistry> reducing agent...
question mark

Why Sn(II) is a reducing agent while Pb(II)is not?

pogula sumanth , 10 Years ago
Grade 12
anser 2 Answers
Sunil Kumar FP

Last Activity: 10 Years ago

The reducing character of element in 4th group is given by
M+2 ------->M+4 +2e-
As stability of the +4 oxidation state decreases down the group,therefore Sn(IV)is more stable as compared to Pb(IV).
For the elements like Sn and Pb to be reducing in (II) state ; they must have stable (IV) state as;

In reducing agent M+2 -> M+4 + 2e-

Now, we know that the inert pair effect increases down the group , so the stability of +4 oxidation state decreases down the group and hence the +4 oxidation state of Pb is less stable than that of Sn .

So, it becomes little difficult for Pb to get converted into its +4 state from its +2 state, so it does not behave as reducing agent.

Sanjay Bahety

Last Activity: 7 Years ago

Because the stability of +4 oxidation state decreases as we go from top to bottom of a group, therefore Pb(||) is not a reducing agent while Sn(||) isCSiGeSnPb

Provide a better Answer & Earn Cool Goodies

star
LIVE ONLINE CLASSES

Prepraring for the competition made easy just by live online class.

tv

Full Live Access

material

Study Material

removal

Live Doubts Solving

assignment

Daily Class Assignments


Ask a Doubt

Get your questions answered by the expert for free