Sunil Kumar FP
Last Activity: 10 Years ago
The reducing character of element in 4th group is given by
M+2 ------->M+4 +2e-
As stability of the +4 oxidation state decreases down the group,therefore Sn(IV)is more stable as compared to Pb(IV).
For the elements like Sn and Pb to be reducing in (II) state ; they must have stable (IV) state as;
In reducing agent M+2 -> M+4 + 2e-
Now, we know that the inert pair effect increases down the group , so the stability of +4 oxidation state decreases down the group and hence the +4 oxidation state of Pb is less stable than that of Sn .
So, it becomes little difficult for Pb to get converted into its +4 state from its +2 state, so it does not behave as reducing agent.