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Dear student
As above answer is not so visible due to text colour, I am posting the same in black text colour
Cr2+ is a reducing agent
while Mn3+ is an oxidizing agent
in spite of both having d4 configuration.
When Cr2+ gets oxidized to Cr3+ (d3),
it attains a stable half-filled t2g orbitals
but when Mn3+ gets reduced to Mn2+ (d5),
it attains a stable half-filled d orbitals.
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