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Grade 12th passInorganic Chemistry

What is the hybridisation of cobalt in [Co(H2O)6]+3. Is water a strong or weak ligand.please Explain.

Profile image of Ankit Dash
7 Years agoGrade 12th pass
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2 Answers

Profile image of Arun
7 Years ago

Co(H2o)6]3+—-

In this complex compound the total chare is +3 as H2o is neutral compound so the oxidation state of cobalt is +3 . and the electronic conf. Of Co is 3d7 4s2 so, Co(+3)=4d6 .nd H2o is weak ligand so there is no pairing of electron so,4 S 4p3 and4 d2 ,orbital make hybrid orbital to have a hybridization of sp3d2 .

 

H2O is a weak ligand

Profile image of Kaustubh das
5 Years ago
  1. It is an exception and therefore its hybridisation is d2 sp3.
  2. The reason behind its nature is due to high Z effective of Co that forces water to behave like strong field ligand.
  3. Water in general is weak field ligand.
  4. For field strength u can refer jd lee spectrochemical series as it is nicely mentioned there
  5. Dont be worried whatever i said is 100% correct and have faith on me as i am also a jee aspirant.
  6. All the best for ur future.