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Electronic configuration of Cu+ is :
1s2 2s2 2p6 3s2 3p6 3d10 4s1
But the expected one is :
1s2 2s2 2p6 3s2 3p6 3d9 4s2
This can be explained on the basis that fully filled orbitals are more stable due to symmetry and more amount of exchange energy. So one elecron jumps from 4s to 3d.
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