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what is meant by lanthanoid contraction in p block of class 12 th chemistry what is meant by lanthanoid contraction in p block of class 12 th chemistry
Lanthanoidcontraction, also calledlanthanide contraction, in chemistry, the steady decrease in the size of the atoms and ions of the rare earth elements with increasing atomic number from lanthanum (atomic number 57) through lutetium (atomic number 71)
The lanthanide contraction is the greater-than-expected decrease in ionic radii of the elements in the lanthanide series from atomic number 57, lanthanum, to 71, lutetium, which results in smaller than otherwise expected ionic radii for the subsequent elements starting with 72, hafnium.This effect occurs due to poor shielding of nuclear charge (nuclear attractive force on electrons) by 4f electrons; the 6s electrons are drawn towards the nucleus, thus resulting in a smaller atomic radius.
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