What is conformation isomerism in coordination chemistry?
What is conformation isomerism in coordination chemistry?
Ankit Dash , 6 Years ago
Grade 12th pass
Inorganic Chemistry> What is conformation isomerism in coordin...
1 Answers
Arun
Conformational isomerism is a form of stereoisomerism in which the isomers can be interconverted exclusively by rotations about formally single bonds (refer to figure on single bond rotation). Such isomers are generally referred to as conformational isomers or conformers and, specifically, as rotamers. Rotations about single bonds are restricted by a rotational energy barrier which must be overcome to interconvert one conformer to another. Conformational isomerism arises when the rotation about a single bond is relatively unhindered. That is, the energy barrier must be small enough for the interconversion to occur.
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