badge image

Enroll For Free Now & Improve Your Performance.

×
User Icon
User Icon
User Icon
User Icon
User Icon

Thank you for registering.

One of our academic counsellors will contact you within 1 working day.

Please check your email for login details.
MY CART (5)

Use Coupon: CART20 and get 20% off on all online Study Material

ITEM
DETAILS
MRP
DISCOUNT
FINAL PRICE
Total Price: Rs.

There are no items in this cart.
Continue Shopping
Menu
Grade: 12th pass

                        

[Ti(H 2 O) 6 ] 3+ shows an ansymmetrical broad absorption line explain it

2 months ago

Answers : (1)

AMIT
15 Points
							
The spectrum you observe is the transition from the ground state 2T2g to the excited state 2Eg of the octahedral aquo ion. It is allowed with respect to the spin rule (DeltaS = 0). The shoulder on the low-energy side is due to Jahn-Teller distortion of the excited 2Eg state. Jahn-Teller (JT) distortions occur when a non-linear molecule is in a degenerate electronic state. The molecule then distorts, its symmetry is lowered and the energy minimized. For Ti(III), d1, the JT distortion of the ground state is small, but the JT of the excited state is sizeable; the 2Eg state splits into 2A1g and 2B1g levels. The splitting is on the order of 2000 cm-1. The band at around 500 nm (20,300 cm-1) corresponds to the transition to 2A1g, the should at around 550 nm to the transition to 2B1g.
2 months ago
Think You Can Provide A Better Answer ?
Answer & Earn Cool Goodies


Course Features

  • 731 Video Lectures
  • Revision Notes
  • Previous Year Papers
  • Mind Map
  • Study Planner
  • NCERT Solutions
  • Discussion Forum
  • Test paper with Video Solution


Course Features

  • 54 Video Lectures
  • Revision Notes
  • Test paper with Video Solution
  • Mind Map
  • Study Planner
  • NCERT Solutions
  • Discussion Forum
  • Previous Year Exam Questions


Ask Experts

Have any Question? Ask Experts

Post Question

 
 
Answer ‘n’ Earn
Attractive Gift
Vouchers
To Win!!! Click Here for details