Flag Inorganic Chemistry> sir please explain that Why CHCl3is more ...
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sir please explain that Why CHCl3is more acidic than CHF3 ?

raju , 9 Years ago
Grade 12th pass
anser 2 Answers
nath

Last Activity: 9 Years ago

Hi !Raju ,
         cl3c- is less basic than F3c- because florine can disperse charge only by an inductive effect while cl(having 3d orbitals) disperses charge by inductive effect as well as by p PIE -p PIE bonding delocalisation.Florine is a second period element with no 2d orbital.
Hope it’s help you,
All the best !!!!
Umakant biswal

Last Activity: 9 Years ago

@ raju 
chf3 when it will be separate into its ions then it will generate cf3- and h+ 
and chcl3 when it will dissociate into ions , it will generate ccl3- and h+ . 
cf3- is not stable by resonance due to the absence of d orbital on F . but ccl3- is stable by resonance due to the presence of d orbital . 
HOPE IT CLEARS YOUR DOUBT 
ALL THE BEST ..
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