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Grade 12Inorganic Chemistry

rate of first order reaction is 0.04 moles (sec litres)inverse at 10 minutes and 0.003 moles (litres sec) at 20 minutes from start .then calculate half life for reaction

Profile image of PUPPALA SURYASAIKIRAN
7 Years agoGrade 12
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1 Answer

Profile image of Arun
7 Years ago
Dear student
 
Reaction type : 1st order reaction

Formula used :

k =( 2.303/t2-t1) log([R1]/[R2])

Given :
T1 = 10 min and T2 = 20 min therefore T2-T1 = 10 min

[R1] = 0.04 mol/L  and  [R2] = 0.03 mol/L

Substituting the values in the above equation

k =( 2.303/10) log( 0.04/0.03)

k = 0.2303 [log(0.04) - log (0.03)]

k = 0.2303 [-1.3979 - (-1.5228)]

k = 0.02876 /min

For the first order reaction half life t1/2 is given by

t1/2 = 0.693/k

We know,  k = 0.02876 we get

t1/2 = 0.693/0.02876

t1/2 = 24.096 min