PCl5 exists in two form in solid state..what is the name of this phenomenon?
Jitender Sharma , 7 Years ago
Grade 12th pass
Inorganic Chemistry> PCl5 exists in two form in solid state..w...
1 Answers
Ravleen Kaur
Last Activity: 5 Years ago
In polar solvents, PCl5 undergoes autoionization. Dilute solutions dissociate according to
PCl5 ⇌ [PCl 4 ]+ Cl− (tetrahedral)
At higher concentrations, a second equilibrium becomes more prevalent:
2 PCl5 ⇌ [PCl 4 ] + and ( [PCl 6 ] - octahedral)
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