Grade 12th passInorganic Chemistry
PCl5 exists in two form in solid state..what is the name of this phenomenon?
PCl5 exists in two form in solid state..what is the name of this phenomenon?
1 Answer
Ravleen Kaur
In polar solvents, PCl5 undergoes autoionization. Dilute solutions dissociate according to
PCl5 ⇌ [PCl 4 ]+ Cl− (tetrahedral)
At higher concentrations, a second equilibrium becomes more prevalent:
2 PCl5 ⇌ [PCl 4 ] + and ( [PCl 6 ] - octahedral)
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