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Grade 12th passOrganic Chemistry

MgCO3 is thermally less stable than CaCO3.explain why?

Profile image of Shreya
9 Years agoGrade 12th pass
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4 Answers

Profile image of Umakant Biswal
9 Years ago
caco3 is more stable than mgco3 beacuse thermal stability of carbonates of group 2 will increase down the group with the increase in the size of cation . 
this is beacuse longer cation will stabilize the larger carbonate ion . 
HOPE IT CLEARS 
regards 
kindly approve 
Profile image of Khimraj
9 Years ago
The thermal stability of carbonate of alkaline earth metal increases down the group. So carbonate of Ca is more stable than carbonate of Mg
Profile image of Subho Sutradhar
8 Years ago
CaCo3 is larger in size compared to MgCo3.As we know larger cation can stabilize a larger anion better so obviously Caco3 is more stable than Mgco3
Profile image of PRATYUSH MONDAL
8 Years ago
Ionic potential is more then thermal stability is less......we know that ionic potential=cataonic charge/cataionic redius....
mg has less cataionic redius than ca......thus it prooves