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Hybridization of fe in brown ring complex and why fe is in +1 oxidation state . I think fe is stable in only +2 and +3 .

Hybridization of fe in brown ring complex and why fe is in +1 oxidation state . I think fe is stable in only +2 and +3 .

Grade:12

2 Answers

Vikas TU
14149 Points
3 years ago
Dear Student,
The OS of Fe in Brown ring is +1. The complex shaped is [Fe.NO.5H2O]SO4..The charge on anion is - 2. Subsequently charge on cationic complex must be +2 as ring is electrically unbiased. The charge on Fe on computation turns out to be +2.. Be that as it may, electrontransfer happen from NO to Fe. Thus No and Fe secure a charge of +1 each. 
Consequently the OS of Fe in dark colored ring is +1, because of charge exchange amongst Fe and NO.
Cheers!!
Regards,
Vikas (B. Tech. 4th year
Thapar University)
Nitin patle
19 Points
2 years ago
Earlier it eas thought in brown ring fe oxidation state is 1 but as per spin magntic moment no-1 and fe+3

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