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As you can see there is 5 H20 that is 5 crystal waters.The 5 molecules of water present in the crystal framework of the molecule where four water molecules are coordinated to Cu+2, while one is hydrogen bonded with SO42-
Copper sulfate pentahydrate contains copper(II) in a geometry best described as distorted octahedral. The copper(II) is bound to four water molecules in a square-planar geometry and two oxygen atoms from two sulfate ions (one H2O is H-Bonded here).
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