The bonds oxygen forms.
In both chemicals, there are a pair of Oxygens; however peroxides have the pair of Oxygens directly connected to each other by a single bond. Dioxides have the oxygens individually attached to another atom, each by a pair of double bonds. Oxygen/Oxygen bonds are unstable, and peroxides are powerful oxidizing agents.
An example of peroxide is of course hydrogen peroxideH2O2H-O-O-Hand for dioxide, carbon dioxideCO2O=C=Onote the location of the oxygen atom.
Thanks
Ruchi
Askiitians Faculty