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Grade 12th passInorganic Chemistry

. From the acidic solution containing copper (+2) and zinc (+2) ions, copper can be selectively precipitated using sodium sulphide.

Profile image of Amanat
12 Years agoGrade 12th pass
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1 Answer

Profile image of Kevin Nash
12 Years ago
True : K base sp of CuS is less than K base sp of ZnS. On passing H base 2S in acidic medium, the dissociation of H base 2S is suppressed due to common ion effect and it provides [S^2-] which is just suffi-cient to cross over K base sp of CuS and not K base sp fo ZnS. Thus only CuS gets precipitated.