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Grade 12Inorganic Chemistry

Describe role of NaCN in extraction of silver from silver ore

Profile image of Pooja
9 Years agoGrade 12
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5 Answers

Profile image of Pooja
9 Years ago
Extraction of SilverRole of NaCN or KCN = In the extraction of gold and silver, the metal is leached with NaCN or KCN, which is an oxidation reaction.During the process, Ag is oxidised to Ag+ .Here M =Ag or Au.Subsequent reaction with Zn leads to formation of free metal.
Profile image of Umakant biswal
ApprovedApproved Tutor Answer9 Years ago
dear pooja ,
in the extraction of gold and silver , the metal is leached with NACN or Kcn , which is an oxidation reaction , 
2- during this process Ag is oxidised to Ag + 
then the reaction with zn result in formation of free metal 
, if u want me to mention the reaction , then let me know , 
HOPE IT CLEARS 
REGARDS 
Profile image of Muskan Kharbanda
8 Years ago
Role of NaCN in the extraction of silver (Ag) is to do the leaching of Ag ore in the presence of air from which the silver is obtained later by replacement.4Ag + 8CN- + 2H2O + O2 → 4 [Ag(CN)2-] + 4OH-
Profile image of Md Sohail
8 Years ago
Silver and gold ores containing native metal are leached with a dilute solution of Sodium cyanide(NaCN) {or Potassium cyanide(KCN) } in the presence of air.This is an oxidation reaction. During this process Ag is oxidised to Ag + , then the reaction with Zn result in formation of free metal.Ag2S + 4NaCN --> 2Na[Ag(CN)2] + 4Na2S2Na[Ag(CN)2]+Zn --->Na2[Zn(CN)4]+4Ag(ppt.)
Profile image of Kushagra Madhukar
6 Years ago
Dear student,
Please find the solution to your problem below.
 
In the extraction of gold and silver , the metal is leached with NACN or KCN , which is an oxidation reaction, during this process Ag is oxidised to Ag+ then the reaction with Zn result in formation of free metal.
Ag2S + 4NaCN → 2Na[Ag(CN)2] + 4Na2S
2Na[Ag(CN)2] + Zn → Na2[Zn(CN)4] + 4Ag(ppt.)
 
Hope it helps.
Thanks and regards,
Kushagra