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define isomerism and structural isomerism?

define isomerism and structural isomerism?


4 Answers

669 Points
6 years ago
Structural Isomerism:
1.Linkage isomerism
; Linkage isomerism arises in a coordination compound containing ambidentate ligand, NCS which may bind through the nitrogen to give M-NCS or through sulphur togive M-SCN.E.g.:35 2 2[( )( )]CoNH NO Cl,( red form) in this the nitrite ligand is bound through nitrogen2()NO− And35 2[( )( )]CoNH ONO Cl(yellow form) in which the nitrite ligand is bound through oxygen, (-ONO),2. Coordination Isomerism? This type of isomerism arises from the interchange of ligands between cationic and anionic entities of different metal ions present in a complex.
E.g.:36 6[ ( )][ ( )]CoNH CrCNand36 6[( )][( )]CrNH CoCN
3. Ionization Isomerism :
This form of isomerism arises when the counter ion in a complex salt is itself a potential ligand and can displace a ligand which can then become the counter ion.
E.g.:35 4[( ) ]CoNH SO Brand35 4[( ) ]CoNH BrSO are ionization isomers.
669 Points
6 years ago
Isomerism is the phenomenon whereby certain compounds, with the same molecular formula, exist in different forms owing to their different organisations of atoms. The concept of isomerism illustrates the fundamental importance of molecular structure and shape in organic chemistry.
26 Points
6 years ago
STRUCTURAL ISOMERISM This page explains what structural isomerism is, and looks at some of the various ways that structural isomers can arise. What is structural isomerism?What are isomers?Isomers are molecules that have the same molecular formula, but have a different arrangement of the atoms in space. That excludes any different arrangements which are simply due to the molecule rotating as a whole, or rotating about particular bonds.For example, both of the following are the same molecule. They are not isomers. Both are butane.There are also endless other possible ways that this molecule could twist itself. There is completely free rotation around all the carbon-carbon single bonds.Note: Isomerism is much easier to understand if you have actually got some models to play with. If your school or college hasn`t given you the opportunity to play around with molecular models in the early stages of your organic chemistry course, you might consider getting hold of a cheap set. The models made by Molymod are both cheap and easy to use. An introductory organic set is more than adequate. Google molymod to find a supplier and more about them, or have a look at this set or something similar from Amazon.Share the cost with some friends, keep it in good condition and don`t lose any bits, and resell it via eBay or Amazon at the end of your course.Alternatively, get hold of some coloured Plasticene (or other children`s modelling clay) and some used matches and make your own. It`s cheaper, but more difficult to get the bond angles right.If you had a model of a molecule in front of you, you would have to take it to pieces and rebuild it if you wanted to make an isomer of that molecule. If you can make an apparently different molecule just by rotating single bonds, it`s not different - it`s still the same molecule.Note: It`s really important that you understand this. If you aren`t sure, then you must get hold of (or make) some models.What are structural isomers?In structural isomerism, the atoms are arranged in a completely different order. This is easier to see with specific examples.What follows looks at some of the ways that structural isomers can arise. The names of the various forms of structural isomerism probably don`t matter all that much, but you must be aware of the different possibilities when you come to draw isomers.Types of structural isomerismChain isomerismThese isomers arise because of the possibility of branching in carbon chains. For example, there are two isomers of butane, C4H10. In one of them, the carbon atoms lie in a "straight chain" whereas in the other the chain is branched.Note: Although the chain is drawn as straight, in reality it`s anything but straight. If you aren`t happy about the ways of drawing organic molecules, follow this link.Use the BACK button on your browser to return to this page. Be careful not to draw "false" isomers which are just twisted versions of the original molecule. For example, this structure is just the straight chain version of butane rotated about the central carbon-carbon bond.You could easily see this with a model. This is the example we`ve already used at the top of this page.Pentane, C5H12, has three chain isomers. If you think you can find any others, they are simply twisted versions of the ones below. If in doubt make some models.Position isomerismIn position isomerism, the basic carbon skeleton remains unchanged, but important groups are moved around on that skeleton.For example, there are two structural isomers with the molecular formula C3H7Br. In one of them the bromine atom is on the end of the chain, whereas in the other it`s attached in the middle.If you made a model, there is no way that you could twist one molecule to turn it into the other one. You would have to break the bromine off the end and re-attach it in the middle. At the same time, you would have to move a hydrogen from the middle to the end.Another similar example occurs in alcohols such as C4H9OHThese are the only two possibilities provided you keep to a four carbon chain, but there is no reason why you should do that. You can easily have a mixture of chain isomerism and position isomerism - you aren`t restricted to one or the other.So two other isomers of butanol are:Note: It`s essential if you are asked to draw isomers in an exam not to restrict yourself to chain isomers or position isomers. You must be aware of all the possibilities.You can also get position isomers on benzene rings. Consider the molecular formula C7H7Cl. There are four different isomers you could make depending on the position of the chlorine atom. In one case it is attached to the side-group carbon atom, and then there are three other possible positions it could have around the ring - next to the CH3 group, next-but-one to the CH3 group, or opposite the CH3 group.Functional group isomerismIn this variety of structural isomerism, the isomers contain different functional groups - that is, they belong to different families of compounds (different homologous series).For example, a molecular formula C3H6O could be either propanal (an aldehyde) or propanone (a ketone).There are other possibilities as well for this same molecular formula - for example, you could have a carbon-carbon double bond (an alkene) and an -OH group (an alcohol) in the same molecule.Another common example is illustrated by the molecular formula C3H6O2. Amongst the several structural isomers of this are propanoic acid (a carboxylic acid) and methyl ethanoate (an ester).
E.Nandhini ketha
115 Points
3 years ago
the relation of two or more compounds, radicals, or ions that are composed of the same kinds and numbers of atoms but differ from each other in structural arrangement (structural isomerism) as CH3 OCH 3 and CH 3 CH 2 OH, or in the arrangement of their atoms in space and therefore in one or more properties.

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