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For gaseous mixture 80% O2, 20% of other gas m
Average molecular weight Mm = 32 (for O2) × 80 + 20 × m / 100
Now, for diffusion of gaseous mixture and pure O2
rO2 / rm = √Mm / MO2 or VO2 / EO2 × Em / Vm = √Mm / MO2
∴ 1 / 224 × 234 / 1 = √Mm / 32
∴ Mm= 34.92
∴ 32 × 80 + 20 × m / 100 = 34.92
∴ m = 46.6
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