SAGAR SINGH - IIT DELHI
Last Activity: 14 Years ago
Dear rohini,
The weak field and strong field ligands are based on their capability of splitting. And are represented in Spectrochemical Series which is a derived list of ligands ordered by the size of the splitting Δ that they produce. It can be seen that the low-field ligands are all π-donors (such as I-), the high field ligands are π-acceptors, such as CN- and CO), and ligands such as H2O and NH3, which are neither strong or weak , are in the middle.
I− < Br− < S2− < SCN− < Cl− < NO3− < N3− < F− < OH− < C2O42− < H2O < NCS− < CH3CN < py (pyridine) < NH3 < en (ethylenediamine) < bipy (2,2'-bipyridine) < phen (1,10-phenanthroline) < NO2− < PPh3 < CN− < CO
(Order of Increasing splitting weak field to strong field).
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Sagar Singh
B.Tech IIT Delhi