FITJEE
Last Activity: 11 Years ago
Disproportionation, is a specific type of redox reaction in which a species is simultaneously reduced and oxidized to form two different products.
For example: the UV photolysis of mercury(I) chloride Hg2Cl2 → Hg + HgCl2 is a disproportionation. Mercury (I) is a diatomic dication Hg22+. In this reaction thechemical bond in the molecular ion is broken and one mercury atom is reduced to mercury (0) and the other is oxidized to mercury (II). A similar type of reaction, but in which no element changes oxidation number, is the acid-base disproportionationreaction observed when an amphiprotic species reacts with itself. Two common examples for conjugated bases of polyprotic acids such as bicarbonate anddihydrogenophosphate are respectively:
- HCO3- + HCO3- → CO32- + H2CO3
- H2PO4- + H2PO4- → HPO42- + H3PO4
(the oxidation numbers remain constant in these acid-base reactions: O = 2-, H = 1+, C = 4+, P = 5+). This is also called autoionization.
The reverse of disproportionation, when a compound in an intermediate oxidation state is formed from compounds in lower and higher oxidation states, is calledcomproportionation.