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NH4+ Ion does not act as ligand because nitrogen atom has no lone pair ofelectrons which it can donate to metal atom.
Complexes are generally formed by donation of a pair of electrons from the ligand to metal; as NH3 with a lone pair on nitrogen can form complexes but NH4+ does not have it.So,it can''t.
or
Proton spin lattice relaxation by NH4+ ion motions and spin diffusion in some ammonium compounds
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